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IOTA 616 Hydride-Terminated Silicone Oil — A Bifunctional Si–H Platform for Precision Silicone Engineering

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Product Overview

In advanced silicone chemistry, structure defines performance, and terminal functionality determines reactivity.

IOTA 616 is a hydride-terminated linear polydimethylsiloxane featuring reactive Si–H groups at both chain ends. This well-defined bifunctional structure makes it a critical intermediate in hydrosilylation, block copolymer synthesis, and addition-cure silicone systems.

Unlike random hydrogen-containing silicone fluids, IOTA 616 concentrates reactive sites exclusively at the chain termini, enabling predictable reaction pathways, reduced side reactions, and highly controlled polymer architecture design.

It is not merely a raw material — it is a structural foundation for engineered silicone materials.


Basic Information

Chemical Name: Hydride-Terminated Silicone Oil
Synonym: Hydride-Terminated Polydimethylsiloxane
CAS No.: 70900-21-9
Appearance: Colorless transparent liquid
Purity: ≥100%


Typical Technical Data

Viscosity (25°C, mPa·s) Molecular Weight H% Density Refractive Index
2–3 500–600 0.5 0.90 1.395
100 6000 0.04 0.97 1.403
500 17200 0.01 0.97 1.403
1000 28000 0.007 0.97 1.403
10000 62700 0.003 0.97 1.403

Different viscosity grades allow precise control over crosslink density and reaction kinetics.


Key Advantages

Bifunctional High-Reactivity Si–H Structure

Reactive Si–H groups at both ends enable efficient hydrosilylation with vinyl- or allyl-functional compounds under platinum catalysis, ensuring controlled and predictable polymer growth.

Designed Reactivity

By adjusting molecular weight and hydride content, users can fine-tune:

  • Crosslink density

  • Chain extension length

  • Hardness

  • Elongation at break

  • Elastic modulus

This flexibility supports advanced material engineering.

Excellent Compatibility

Compatible with various silicone systems and organic polymers, IOTA 616 acts as an effective structural bridge in hybrid silicone-organic materials.

Reliable Industrial Stability

Consistent quality and structural stability make it suitable for scalable industrial production and high-end material manufacturing.

Hydrophobic Performance

Similar to IOTA 202 and IOTA 203, it provides excellent moisture resistance and long-term hydrophobicity.


Applications

Hydrosilylation Intermediate

Widely used to synthesize:

  • Epoxy-modified silicones

  • Amino-functional silicones

  • Polyether-modified silicones

  • Terminal-functional siloxanes

Its terminal structure ensures reaction precision and minimized side reactions.


Block Copolymer Synthesis

Serves as a bridging unit in silicone-organic block copolymer systems, widely applied in:

  • Functional coatings

  • Sealants

  • Flexible elastomers

  • Specialty polymers


Addition-Cure Silicone Systems

Used as a chain extender or crosslinker in LSR and HTV systems to:

  • Increase elongation

  • Improve toughness

  • Reduce hardness

  • Optimize mechanical balance


Organic Polymer Modification

Acts as a starting material for resin modification, improving flexibility, surface slip, weather resistance, and moisture protection in plastics and coatings.


Conclusion

IOTA 616 is a bifunctional reactive platform enabling controlled silicone architecture design.
Its terminal Si–H structure delivers precision, reliability, and performance across hydrosilylation and addition-cure systems.

For advanced silicone engineering, IOTA 616 provides the structural control your formulations demand.

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