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Di-Functional Acrylate Silicone Oil for UV-Curable Systems

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Introduction

Acrylate silicone oils are widely used in UV-curable systems to enhance surface performance and durability. Among them, di-functional (double-end) acrylate silicone oils represent a higher level of reactive silicone modification.

IOTA 2220 is a polydimethylsiloxane compound terminated at both ends with acrylate functional groups, designed specifically for UV-curable resin systems.


Structural Characteristics

Unlike mono-functional acrylate silicones, IOTA 2220 contains two acrylate groups located at both ends of the silicone chain. This di-functional structure allows the silicone segment to participate directly in the crosslinked polymer network during UV curing.

As a result:

  • The silicone chain becomes an integral part of the cured film

  • Migration and surface blooming are effectively eliminated

  • Long-term performance stability is significantly improved


Reaction Mechanism in UV Systems

During UV curing:

  1. Both acrylate end groups undergo free-radical polymerization;

  2. The silicone chain acts as a flexible spacer within the network;

  3. Silicone segments preferentially enrich at the surface due to low surface energy;

  4. A stable, silicone-modified coating structure is formed.

This mechanism ensures permanent silicone modification rather than temporary additive effects.


Performance Advantages

  • Long-lasting soft and smooth surface feel at low dosage (0.2–1%)

  • Excellent anti-stain and easy-clean properties at higher dosage (2–6%)

  • Improved weather resistance and UV durability

  • Enhanced low-temperature flexibility

  • Balanced mechanical properties without excessive brittleness


Molecular Weight Options

  • MW ~2000: Better flow, leveling, and tactile performance

  • MW ~4000: Enhanced durability, anti-stain performance, and weather resistance


Applications

IOTA 2220 is suitable for:

  • UV-curable coatings and inks

  • Functional surface coatings

  • Anti-fouling and easy-clean systems

  • High-performance UV resin formulations


Conclusion

Di-functional acrylate silicone oil offers a structural approach to silicone modification in UV-curable systems. By chemically integrating silicone segments into the crosslinked network, IOTA 2220 delivers long-term surface performance, durability, and flexibility, making it an ideal choice for advanced UV coating applications.

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